Can not send e-mails after iOS5 upgrade

I upgraded my wifes iPhone to iOS 5. After the upgrade she can receive e-mails but can not send them. All the composed e-mails end up in her outbox. I click on the error and it says "The connection to the outgoing server "smtp.***.com" failed. Additional Outgoing Mail Servers can be configured in Setting>Mail, Contacts, Calenders."
Anyone have any suggestions?

Go to Settings => Mail,Contacts,Calenders => select the account and may have to click account again => should be viewing username and password, Scroll down and Select - Outgoing Server => Tap on Primary Server => try entering Username and Password in there even though it says optional... Also try port 25 if that doesn't work and try toggling SSL on/off if that doesn't work.

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