Can't get rid of old smtp option

I have changed ISP. Therefore, my smtp server is different, and I have changed it under Accounts, and have edited my listings of smtp servers to delete the server for the former ISP. Nonetheless, whenever I send a mail message, the defunct smtp server is listed (usually as the default) in the selection for the outgoing mail. How do I get rid of that listing?
There is no Help item for this, and no one seems to know where that information is stored. Is it on a plist somewhere? If you know, please be specific.
Incidentally, does it not seem that when an smtp is deleted from the list, it should get lost, and not keep popping up again?

You should be able to view the contents of com.apple.mail.plist in human readable form with Property List Editor, which is included with the Developer tools, or with one of the third-party property list editors available out there, such as Pref Setter or PlistEdit Pro.
Anyway, if you cannot get rid of that setting by normal means, you may re-create the preferences file as follows:
1. If you have a .Mac account and .Mac synchronization of Mail data is enabled either in Mail > Preferences > General or in System Preferences > .Mac, disable it before proceeding.
2. Quit Mail if it’s running.
3. Make a backup copy of the ~/Library/Mail folder, just in case something goes wrong while trying to solve the problem. You can do this in the Finder by dragging the folder to the Desktop while holding the Option (Alt) key down, for example. This is where all your mail is locally stored.
4. In the Finder, go to ~/Library/Preferences/. Locate com.apple.mail.plist and move it to the Desktop (to be deleted if this fixes the problem).
5. Open Mail. You’ll have to set up your non-.Mac accounts from scratch all over again. If given the option to import existing mailboxes or something like that, don’t. Just enter the account information and Mail will automagically rediscover the data in ~/Library/Mail/ when done.
6. You’ll have to re-configure most of your settings in Mail > Preferences. For spam-related security reasons, the first thing you should do is go to Preferences > Viewing and disable Display remote images in HTML messages if it’s enabled.
7. You may also need to re-install or re-enable any Mail plug-ins you have installed for Mail to recognize them.
8. As a side effect of re-creating com.apple.mail.plist, Mail might rename Outbox (which is where messages waiting to be sent are stored) to Delivered. The name of that mailbox is actually a misnomer, as it would contain messages (if any) that couldn’t be delivered for some reason. You can delete that mailbox if you wish.
9. If the problem is fixed now and .Mac synchronization of Mail data was enabled at the beginning, enable it again, go to System Preferences > .Mac > Advanced, click Reset Sync Data, and choose the appropriate options to reset the Mail data stored on the .Mac server with the data locally stored on the computer, i.e. sync data must flow from the computer to the .Mac server.
Note: For those not familiarized with the ~/ notation, it refers to the user’s home folder. You can easily locate any of the folders referred to in this post by copying the folder path here, doing Go > Go to Folder in the Finder, and pasting the folder path there.

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