HOW DO I SEND AN EMAIL AND SHOW IT COMING FROM A DIFFERENT ADDRESS?

Hi All.
I'm a newbie to the iMac, having taken receipt yesterday and currently trying to set up email - can anyone help please?
I have a business email address attached to my domain name that I like to appear on all emails I send and be the default address sent to once reply is hit.
This was easily achieved in in MS Outlook on my old desktop where the email was sent through a TalkTalk account, but showed my business email address, but so far does not appear possible in Mail.
I understand there are issues between TalkTalk and Apple, so have alternate accounts with BTInternet and Gmail, but cannot achieve the desired result with those either. Despite surfing the net for the best part of the day looking for answers I'm no further forward, can anyone shed light on a solution please?

In order for the "From" field to show you options on the "from" addresses available, you must set them up in the Preferences > Accounts first.
I can't show you a screen shot of the from field because I currently only have one account, so the from address used is the default. However, when I had more than one, then options will show up in your compose/reply window.
You'd need to add an account here:

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