I have 2 email addresses set up on my iphone 5, 1 can send mail and the other can't... have tried deleting and adding the account, no luck, have tried all suggestions... anyone help?

I have recently purchased the iphone 5S and have two AOL email accounts set up on it. They could both receive and send mail on the first day, but from the second day only 1 can send mail (both still receive). I get an message saying "Unable to send mail. A copy has been placed in your Outbox. Sending the message content to the server failed." This has been the response now for 3 days and suddenly this morning, I was able to send an email from this account, but only the one and now it's back to that same message. I have deleted and added the account again, using various methods. I even reset my phone and set it all up again from beginning with no luck. It is very frustrating and I am unsure why I can't send from both accounts, especially being that they are the same provider. I have read forums and it appears many have this same problem and I wondered if anyone has had it recently on this phone and how they fixed it. Someone said just use the AOL app to send from this account, yes that can be done, but it's inconvenient having to sign in all the time when i have a mail app that should work automatically. Any suggestions would be welcomed!!

I am not sure if this issue is going to help you but lets give it a try.
I know that where im from, which is the Netherlands, I am not able to sent e-mails from my iPhone or any other mobile device by using 3G or a random WIFI acces point. The provider only allowes you to sent e-mails when you are connected to a network of there own. Which means if you have provider "101" and your email settings are set up for this provider in your iPhone but your using the network of a friend of yours which is provider "202" you cannot sent emails from his network. Though you can receive them you may not sent.
As I said, I am not aware if this issue is the same for you totaly depents on the country and provider your using.

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