One of the users on my Mac book pro, running Mountain lion finds that no changes made in last session are there next time they log on

One of the users on my Mac book pro running mountain lion finds that no changes made in last session are there next time they log on.
For instance, the Macintosh HD icon, is always moved so that it is almost off the screen to top left hand side of the desktop.
None of my changes to the sidebar in the finder are there.
My changes to the dock have reverted.
Despite unticking the box when logging out, even though i have quit all applications, iphoto and safari are always re-opened.
iphoto always says the library needs to be upgraded... even though i did that the last time.
I have tried deleting ALL the files in the "Saved application state" folder in the library folder, but that doesn't seem to make any difference.
This is on a second admin user account.
The main user account seems to be fine.
This account used to be in the filevault on Lion, but is not now in Mountain Lion.
Can anyone help?
Thanks

The same tragic thing happened to me, not even a full two days after I bought it. I immediately powered it off, wiped it as best I could, and put it in front of a fan. I tried valiantly to get the back off, but couldn't remove all the screws. I was basically inconsolable until I realized that no matter what, my credit card insurance would cover it, since it had been less than 90 days. Fast forward 48 hours, and it seemed to run just fine. Some of the keys and the track pad were sticky, and I figured since it was covered, I might as well get it fixed. My only concern at this point was had I voided the Apple Care. I brought it in, told them what happened, said what I needed to satisfy the credit card, and they said, "We'll just swap it out for you, no problem." I was thrilled, and the Genius said they appreciated my honesty, and it was easier for all parties to just do it this way. And my Apple Care was transferred to the new machine. This was my first Mac and, needless to say, I am now an Apple devotee.

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