Outlook refuses to add another exchange account on the same computer on another Local User Account

So at home I have a family computer with some computer accounts. 
at two of them, I installed Outlook 2013. On the first one, I added a existing Exchange account, and everything went well.
but when I tried adding another existing Exchange account (on the same domain) Outlook displayed this message about 'not being able to set up a secure connection'. both the accounts existed and are working. 
Is this because of the secure mail port (465) was already occupied? 
what do I have to do?
please help me!

Hi,
I understand that you setup one Exchange account on the first local account successfully, but failed to setup the second Exchange account on the second local account.
As for the question "Is this because of the secure mail port (465) was already occupied? " I don't think it's the cause, but anyway, we can temporarily remove the first Exchange account from the first local account, and then try to add
the second Exchange to the Second local account and see if the account can be configured successfully.
I'd also like to know whether these accounts are local administrators or standard users, are the different permissions making a difference?
If there's anything that I misunderstood, please feel free to let me know.
Regards,
Melon Chen
TechNet Community Support
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