Some Users on randomly basis unable to send mails from 2003 exchange to 2007 Exchange users Internally.

Hi All,
Some Users on randomly basis are unable to send e-mails from 2003 exchange to 2007 Exchange users Internally.
They are sending mails from outlook and users from 2007 dont have any issues.
But sometime mails from 2003 to 2007 goes without any issue.
The NDR reported is as below.
From: System Administrator
Sent: 22 February 2014 15:59
To: XYZ
Subject: Undeliverable: Regarding Test Message
Your message did not reach some or all of the intended recipients.
Subject: Regarding Test Message
Sent: 22/02/2014 15:59
The following recipient(s) could not be reached:
XXX,XYZ on 22/02/2014 15:59
The message contains a content type that is not supported
<HubServer.Domain.UK #5.6.0 smtp;554 5.6.0 STOREDRV.Deliver.Exception:PropertyValidationException; Failed to process message due to a permanent exception>

Hi,
According to the NDR, I found this point "The message contains a content type that is not supported".
Please verify whether the un-delivered messages contain some Sensitive
Information, signatures or attachments that cannot pass the Exchange 2007 Edge server. Please also check the content type of the un-delivered messages.
Found a useful KB for your reference:
Frequently asked questions about MIME and content conversion in Exchange 2000 Server and in Exchange Server 2003
http://support.microsoft.com/kb/836555/en-us
Hope it is helpful
Thanks
Mavis
Mavis Huang
TechNet Community Support

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