2006 Mac Pro Cold Boot Failure

Hi all,
I have problems with 2006 Mac Pro. It fails cold boot at 100%, first thing in the morning only. So I'm seeking expert advice.
The spec is,
Xeon 5355 2.66GHz x2 (Octo cores)
ATI Radeon 5770(Apple Genuine)
8GB Memory(4x1GB kingston, 4x1GB OWC)
500GBx2 1TBx2 HDDs
I disassembled and cleaned PSU and Fans, reapplying thermal pastes on CPUs and North Bridge a month ago.
Then I booted, system froze at desktop, so I shut it down, reset PRAM & SMC. it booted normally but the upper riser card wasn't detected at all. I cleaned the slot contact and reseated DIMM modules. It was detected after that.
Everything worked fine for a few days but then I got random kernel panics, reseated RAM, reinstalled Snow Leopard but still got random kernel panics. Then ran AHT for a couple of hours and got an error code 4MEM/6....
I contacted OWC and they sent me a new set of memory modules. While waiting for the replacement, no kernel panics at all but DVD drive died as well as IDE cable, so I replaced both.
I got the replacement RAM but past a week, MP fails cold boot every morning. Below is what's happening...
(1) With Kingston Memory, CPU B error LED is lit, I press SYS_RST, one of DIMM LED is then lit (always DIMM A1). Or sometimes, Power-LED is blinking.
(2) With OWC memory, boots normally, then kernel panic within a few minutes.
(3) With OWC memory, CPU B error LED is lit, I press SYS_RST, one of DIMM LED is then lit (always DIMM B1)
*(1) with new and old riser cards
*(3) after replaced 2 riser cards
Replacing riser cards didn't help. After these happen, I shut down by pressing power button for seconds and it boots normally without a hitch. Never get kernel panics nor system freeze. It means when it warms up, MP just works just like it should.
Replaced so far,
-- IDE cable (Apple Genuine)
-- DVD drive (Optiarc AD-7200A)
-- 4GB (1GBx4) OWC memory
-- RTC battery CR2032
-- 2 riser cards
Is the logic board dead or PSU or memory modules are still bad?
Any ideas?
Thanks

I have a Mac Pro dual 2.8 ghz quad core, circa 2008. Recently, I have been required to depress the power button to end a failed cold boot, then press again to boot, usually with success.
Every hard restart freeze, and can guarantee you end up with
corrupt caches, corrupt file system, corrupt directory.
Safe Boot is not effective in such cases, fsck from single user mode has a better chance.
Booting from another hard drive, install your bought copy of Alsoft Disk Warrior to rebuild the directory (it has deep scavenge files also).
The longer you continue to do just Safe Boot and continue using it, the more trouble and less likelihood of being able to repair the drive.
SMART is not smart enough, it tells you about the past, not what could likely happen, or if you have had bad sectors and I/O errors.
Have bootable backup clones and a drive that is a clean Apple OS and drivers that isn't used except for repairs and maintenance. Don't rely on just Apple Disk Repair.

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