Accidentally Unmounted Boot Camp Partition

Hi,
I had accidentally unmounted my Boot Camp Partition the other day. When I mounted it back using disk utility, it didn't show up under Startup Disk. The partition still shows up on my Desktop and the windows files are still in tact.
This is what Disk Utility showed:
Name : disk0s3
Type : Volume
Disk Identifier : disk0s3
Mount Point : /Volumes/Untitled
File System : Windows NT File System (NTFS)
Connection Bus : Serial ATA 2
Device Tree : /PCI0@0/SATA@1F,2/PRT2@2/PMP@0/@0:3
Writable : No
Universal Unique Identifier : F7D4C476-E67F-41A4-BD31-900E40EA3D21
Capacity : 201.0 GB (215,795,892,224 Bytes)
Free Space : 175.1 GB (187,998,601,216 Bytes)
Used : 25.9 GB (27,797,286,912 Bytes)
Number of Files : 142,474
Number of Folders : 0
* Owners Enabled : No*
Can Turn Owners Off : No
Can Be Formatted : No
Bootable : No
Supports Journaling : No
Journaled : No
Disk Number : 0
Partition Number : 3
When opening Boot Camp Utility, it gives me the following message:
+Boot Camp Assistant cannot be used: You must update your computer's Boot ROM firmware before using this setup assistant.+
My Boot ROM firmware is up to date, Boot ROM Version: MP41.0081.B07
Also, Mac OS takes more than 10 minutes to load during startup. I have never experienced this problem before. Could this be related to the accidental unmount-ing?
Appreciate some help

It's gone, the icons in finder are just icons. You will have to reinstall and restore your backup if you have one.

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    1465149167           1         Sec GPT header
    $ sudo fdisk /dev/disk1
    Disk: /dev/disk1     geometry: 91201/255/63 [1465149168 sectors]
    Signature: 0xAA55
             Starting       Ending
    #: id  cyl  hd sec -  cyl  hd sec [     start -       size]
    1: EE    0   0   2 - 1023 254  63 [         1 - 1268035583]     *2: 07 1023 254  63 - 1023 254  63 [1268035584 -  197111808] HPFS/QNX/AUX
    3: 00    0   0   0 -    0   0   0 [         0 -          0] unused     
    4: 00    0   0   0 -    0   0   0 [         0 -          0] unused

    My setup is very similar to your's, Ryan, on a Mac Mini5,2 and the ordering is different and Winclone was not used.
    1. New Mini with internal 500GB with Mountain Lion(ML), put into an external FW enclosure, so the Mini can/could be booted using an external drive for contigency.
    2. Replaced internal stock HDD (500Gb/5400rpm) with SSD/HDD (256Gb SSD/1TB 5400rpm).
    3. Installed W7 x64 on 64GB partition on HDD, which was a single-partition drive to begin with.
    4. The remaining HDD partition and the entire SSD was put into a Fusion drive.
    5. Using Command-R, new ML installed on Fusion HD.
    Here is what I currently have...(Disk0 - SSD, Disk1- 1TB HDD, Disk2 - Fusion, Disk3 - External FW).
    diskutil list
    /dev/disk0
       #:                       TYPE NAME                    SIZE       IDENTIFIER
       0:      GUID_partition_scheme                        *256.1 GB   disk0
       1:                        EFI                         209.7 MB   disk0s1
       2:          Apple_CoreStorage                         255.7 GB   disk0s2
       3:                 Apple_Boot Boot OS X               134.2 MB   disk0s3
    /dev/disk1
       #:                       TYPE NAME                    SIZE       IDENTIFIER
       0:      GUID_partition_scheme                        *1.0 TB     disk1
       1:                        EFI                         209.7 MB   disk1s1
       2:          Apple_CoreStorage                         934.5 GB   disk1s2
       3:                 Apple_Boot Boot OS X               650.0 MB   disk1s3
       4:       Microsoft Basic Data BOOTCAMP                64.9 GB    disk1s4
    /dev/disk2
       #:                       TYPE NAME                    SIZE       IDENTIFIER
       0:                  Apple_HFS Fusion HD              *1.2 TB     disk2
    /dev/disk3
       #:                       TYPE NAME                    SIZE       IDENTIFIER
       0:      GUID_partition_scheme                        *500.1 GB   disk3
       1:                        EFI                         209.7 MB   disk3s1
       2:                  Apple_HFS Rescue HD               371.8 GB   disk3s2
       3:                  Apple_HFS Leopard HD              31.9 GB    disk3s3
       4:                  Apple_HFS Snow Leopard HD         31.9 GB    disk3s4
       5:                  Apple_HFS Lion HD                 31.3 GB    disk3s5
       6:                 Apple_Boot Lion Recovery HD        650.0 MB   disk3s6
       7:                  Apple_HFS Mountain Lion HD        31.3 GB    disk3s7
       8:                 Apple_Boot Mountain Lion Recove... 650.0 MB   disk3s8
    diskutil cs list
    CoreStorage logical volume groups (1 found)
    |
    +-- Logical Volume Group A8C00490-0E14-401F-AB69-59F37724E8C4
        =========================================================
        Name:         Fusion
        Size:         1190201270272 B (1.2 TB)
        Free Space:   0 B (0 B)
        |
        +-< Physical Volume 4772013B-5520-4801-9BE5-BCAEF4AEDAB3
        |   ----------------------------------------------------
        |   Index:    0
        |   Disk:     disk0s2
        |   Status:   Online
        |   Size:     255716540416 B (255.7 GB)
        |
        +-< Physical Volume A679A101-3C78-4A59-B5EE-A4339210CFAD
        |   ----------------------------------------------------
        |   Index:    1
        |   Disk:     disk1s2
        |   Status:   Online
        |   Size:     934484729856 B (934.5 GB)
        |
        +-> Logical Volume Family 5EF5C7CA-0B9C-4169-82A1-41C84F206672
            Encryption Status:       Unlocked
            Encryption Type:         None
            Conversion Status:       NoConversion
            Conversion Direction:    -none-
            Has Encrypted Extents:   No
            Fully Secure:            No
            Passphrase Required:     No
            |
            +-> Logical Volume 1512657C-ED13-4B31-82C6-7AECBBCA7F98
                Disk:               disk2
                Status:             Online
                Size (Total):       1185508581376 B (1.2 TB)
                Size (Converted):   -none-
                Revertible:         No
                LV Name:            Fusion HD
                Volume Name:        Fusion HD
                Content Hint:       Apple_HFS
    sudo gpt -r -vv show disk1
    gpt show: disk1: mediasize=1000204886016; sectorsize=512; blocks=1953525168
    gpt show: disk1: Suspicious MBR at sector 0
    gpt show: disk1: Pri GPT at sector 1
    gpt show: disk1: Sec GPT at sector 1953525167
           start        size  index  contents
               0           1         MBR
               1           1         Pri GPT header
               2          32         Pri GPT table
              34           6        
              40      409600      1  GPT part - C12A7328-F81F-11D2-BA4B-00A0C93EC93B
          409640  1825165488      2  GPT part - 53746F72-6167-11AA-AA11-00306543ECAC
      1825575128     1269544      3  GPT part - 426F6F74-0000-11AA-AA11-00306543ECAC
      1826844672   126679040      4  GPT part - EBD0A0A2-B9E5-4433-87C0-68B6B72699C7
      1953523712        1423        
      1953525135          32         Sec GPT table
      1953525167           1         Sec GPT header

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