Activation code not working

I own a version of Adobe Photoshop CS2. Sadly a little while ago my PC murdered itself with a Mother Board malfunction (or something of that nature) and the computer had to be tossed. Now that I have a new PC I'm trying to reinstall Photoshop but it is complaining the serial number is invalid.
Tech support, or whoever I was transferred to on the phone, said the serial number was accurate and should be working. The only thing they could discern as an issue was the operating system, which went from Windows XP to Windows 7.
Naturally they tried to tell me it was a compatibility issue but I get no such error message and the program works perfectly when you use the trial version.
But because I've been asked like 10 times today, no I don't have a trial version. I have the full version which allows a trial if you are missing the code. The version I have was purchased as a CD, not a download and I have the serial number on the back of the CD case. My CS2 is an upgrade from Photoshop 5.5, which I also have in front of me with it's activation code. I was told I'd need to type in 5.5's code after getting passed the CS2 activation window, but it's CS2 that's bogging me down and being pragmatic.
I'd like to know how to get the program working. Being told CS2's compatibility issue lies in the acceptance of the serial code is absolutely frustrating. I could understand if the program didn't work at all, but it does. Perfectly. It just won't take my code no matter how many times I type it in and double, triple and quadruple check that I put it in right.
The exact error I'm getting is "You must enter a valid serial number before activating online or viewing activation options. Please check your serial number and re-enter it, or click the Purchase button to buy a copy of this product."

You are running an application on a system for which it was never designed.  Things are changing re: security, and Photoshop CS2 has no knowledge of that.
Try this:
Either run Photoshop "As Administrator", or turn off Windows UAC on your entire system (with required reboot) then run it.
If you DO disable UAC, you might want to read up on what UAC does for you (running your apps with only user privileges, redirecting some disk operations, etc.) and understand the benefits/risks before choosing to leave it disabled.
-Noel

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