Activation of Photoshop Elements once installed

Hello. I've installed Premiere Elements 12 {organizer and video} but am unable to access Photoshop Elements. I am being asked to sign in, which I've done, then asked for a serial number which I've done - message comes up with 'serial number not recognised'.
Can anyone help?
Thanks

Have tried your suggestions. Still no luck.
The full issue is this - I have 1 CD for Premiere Elements 12 which I've installed, the serial number was accepted and I can access the icon for Premiere Elements.
My problem is that when I open up the icon on my pc for Photoshop {which is the programme that I want for photography} I am asked to sign in which I do.
I'm then asked for a serial number, the only one I have is the one I used at the initial installation.  When I attempt to put this serial number in I get the message not recognised.
A

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