Additional email address will receive but not send

My .mac email address works fine, sending and rerceiving in "Mail" I have another email address with virgin.net. which will receive but not send. I get a pop-up window saying "cannot send using smpt mac.com" (this is the server selected for my .mac address account) I have tried selecting the virgin smpt server but that doesn't work either. What should I do?
Thanks for all suggestions
Rob
imac G5 isight   Mac OS X (10.4.2)  

Most, if not all ISPs block the use of SMTP servers that are outside of their network (or not provided by the ISP) on Port 25. Some ISPs allow the use of an authenticated SMTP server only (such as the .Mac SMTP server) that is outside of the network on Port 25 but some block its use regardless.
Sounds like BT Broadband allows the use of an authenticated SMTP server that is outside of their network on Port 25 and the virgin.net SMTP server must not be authenticated.
Are you accessing an email account and SMTP server provided by BT Broadband with the Mail.app?
Something to try.
Go to Mail > Preferences > Accounts and under the Account Information tab for the virgin.net account preferences at the SMTP server selection, select the Server Settings button below.
Enter 587 in place of 25 in the Server Port field and when finished, select OK to save the changed setting.
If this doesn't resolve the problem and you are accessing an email account and SMTP server provided by BT Broadband in Mail, select/use BT Broadband's SMTP server to send mail with your virgin.net account which is invisible to all recipients.
These SMTP server restrictions are in place as part of an overall effort to prevent spam emanating from the ISP's domain.

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