Apple Mail: Email not sending from default account

Note: Default email send worked fine in Mavericks. The issues seems to be new in Yosemite.
I have 3 emails accounts: Exchange, Gmail, Yahoo. In that order. They are placed in that order in the Accounts section of Apple Mail. They are also placed in that order in the mailbox listing under Inbox in mail.
When creating a new email, the top account, Exchange, is rarely chosen as default. Either Gmail or Yahoo are chosen...and occasionally Exchange. I send 90% of my mail from the Exchange SMTP server; now forced to manually change the outbound Account within the mail message itself almost every time.
Again, this is a brand new issue in Yosemite where it doesn't appear to recognize the default account to send email from in Mail.
Anybody else seeing this?

Hi Will, and a warm welcome to the forums!
Tough to tell what you've tried, is this one you've tried...
Safe Boot from the HD, (holding Shift key down at bootup), it will try to repair your Disk Directory while the spinning radian is happening, so let it go, run Disk Utility in Applications>Utilities, then highlight your drive, click on Repair Permissions, then move these folder & file to the Desktop.
Move this Folder to the Desktop...
/Users/YourUserName/Library/Caches/Mail/
Move this file to the Desktop...
/Users/YourUserName/Library/Mail/Envelope Index
Reboot.
PS. Safe boot may stay on the gray radian for a long time, let it go, it's trying to repair the Hard Drive.
Who is your ISP or eMail Provider?

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