Can not send email from corporate account when out of office

I have a 3G+wifi ipad, my sending via corp email works when I'm in the office (connected via wifi) but doesn't send when I'm on 3G and other wifi network (my home wifi). When I send from the other locations I can send from yahoo account only. I have tried to change the server port a couple of times but still no luck. Anyone has any idea how solve this problem?

I am still having some of the problems the guy who can't get corporate emails has.
You have already read my thread. Yesterday was a good day, I got every single email I received on my iPhone and main Mac computer on my iPad.
I powered the Pad down last night, turned it on this morning and only got 2 of the 4 I was sent during the night, 2 of them being from my US HO but yesterday I got emails from my US HO on my iPad early in the evening.
I have learnt that ntl world emails cannot be received with 'Push' so that cancels out that being anything to do with it.
There is only one difference in my settings so don't know if this is making any difference:-
On my iPad the smtp authentication is MD5 Challenge-Response.
On my iPhone the authentication is Password, I have tried changing it but it won't let me. Can't think that this is the problem as this is on the Outgoing Server of which I have no problems.
Another odd thing is that when I got my iPhone last year I synched the account settings through iTunes. I did this 3 weeks ago when I got my iPad. I then unselected synching the accounts in iTunes when the Pad was connected as I wanted to set them up manually. Now I cannot access this part of iTunes for the phone or pad, it's ticked but greyed out and doesn't show any of my 4 accounts.
One of the main reasons I bought a Pad is to do emails on it as I find the iPhone a little small to use all day. I am gutted that the Pad is not getting all mails and can't trust it.
Could it be that when I power down it affects the settings as that's the only thing different I did yesterday. I will keep the pad on all day and night but this should not be the problem can it? Don;t want to waste power having it on all evening.

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