Can not update 5.1.1 to 6.0 on factory unlocked iPhone 4S - An unknown error occurred (-1) (21)

HI all,
for the first time, one of my Apple products is making me mad.
1.) I have an factory unlocked iPhone 4S running 5.1.1
2.) When I try to update, it (MacBook Pro running 10.8.1) extracts the software and then after a few seconds it shows me (An unknown error occurred (-1))
3.) When I put the phone in DFU Mode and try to update it shows me (An unkown error occurred (21)) - The iPhone freezes at the Apple Logo
I have downloaded the IPSW again (Yes I am sure I have the one for iPhone 4S), have downloaded and installed iTunes 10.7. Further I have installed iTunes fresh on a another Laptop (iTunes 10.7 on Windows 7) - Same behavior there.
The funny thing is, when I restore the iPhone to 5.1.1 it restores it without any problem.  I have also tried to first make a restore on 5.1.1 and directly on 6.0. Same problem.
PLEASE HELP ME!
Cheers
Peter

You might try using RedsNow to put it in DFU mode.
Where did you get the .ispw file?
http://appldnld.apple.com/iOS6/Restore/041-7181.20120919.lEuOK/iPhone4,1_6.0_10A 403_Restore.ipsw
Basic troubleshooting steps  
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