Can somone tell me what the use of Dictionary is?

I am learning from the ADobe Flex store project and they use
a dictionary but i have no idea what the point of using such thing
is, i read the reference document and it doesn't really explain? is
it to basically check if the data is absolutely correct? can i use
something else ? can i get an example of how it differs

means my variable was pointing to wrong directtory
ORA_NLS10=/aplvol01/CRP/oracle/CRP/db/tech_st/10.2.0/ocommon/nls/admin/data
so i corrected it to “$ORACLE_HOME/nls/data/9idata”,
started the db, it gor started
ran autoconfig and preclone on dbtier
ran the same on appstier
all worked fine..than i broguht down the db gracefully
than started again and it again gave me the following
ORA-01092: ORACLE instance terminated. Disconnection forced on sql main screen
and alert.log
ORA-12701: CREATE DATABASE character set is not known
so i checked again the ORA_NLS10
and it was back to
[oracle@t1 data]$ echo $ORA_NLS10
/d01/oracle/t1/db/tech_st/10.2.0/ocommon/nls/admin/data
can you tell me what wrong here

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