Can't send email from any account in Mail app

Suddenly, a couple of days ago, Mail started refusing to send mail in my .Mac account. I changed nothing in terms of settings and the way I do stuff. Receiving has been unaffected.
I'm at a loss to think what it could be... any ideas?
Thanks.

Sure your ISP provides some POP and/or IMAP accounts with access to an SMTP server as part of the service. Have you tried sending with that?
In an attempt to fight spam, many ISPs restrict the ability to send using an outgoing (SMTP) server not owned by them, usually by blocking port 25 for all traffic outside their own network, which means you cannot send with an SMTP server not owned by them if configured to use that port number.
Something that often works is changing the outgoing server port to 587 (or whatever alternate port number the outgoing server listens to) instead of 25 and using some form of authentication in Preferences > Accounts > Account Information > Outgoing Mail Server > Server Settings, but two conditions must be satisfied for this change to work: (1) the ISP must not block that port as well AND (2) the outgoing server in question must listen to that port and accept a form of authentication not based on the IP address you’re connecting from.
Independent mail service providers not tied to a particular ISP, such as .Mac and Gmail, do allow authenticated SMTP access on port 587, which is the reason changing the outgoing server port number solves the problem for them if the ISP doesn’t block that port as well:
http://docs.info.apple.com/article.html?artnum=75124
http://mail.google.com/support/bin/answer.py?answer=13275

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