Can't Send Email from Iphone Using Pop Account

I have check our host names, ports, user name, passwords etc (all the account mail settings are OK) for incoming and outgoing servers. I can receive email fine but can't send them back out through the outgoing server. I am using the identical settings that I used in my Treo (which sent out emails fine). Upon sending an email the error message I get on my iphone is: " The recipient [email protected] was rejected by the server." I've noticed that I can send an email to "myself" (from the iphone) and it will show up on the in my email box, but email sent to other addresses will generate the above message. I've noticed, too, that I have to keep resetting the "Authentication" to "Password" (under advance settings) because it mysteriously resets itself to "MD5 Challenge-Response". The setting should be set to "Password" however. We are using a FirstClass email system. Sending email via the iphone by way of .mac, yahoo and gmail works fine (no mysterious rest of the "Authorization" settings either) .
It most me something obvious, but I can't see it.
I would really appreciate some help.

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http://discussions.apple.com/message.jspa?messageID=4976383#4976383

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How can I send email from my yahoo alias account in iPhone5 mail?
I have 2 email accounts: [email protected] is an alias of [email protected]
In my old iPhone3 I had these accounts set up so that I could send and receive email from both accounts. I did this using the following settings:
‘Other’ POP account info:
Name: xyz
Address: [email protected]
Description: alias
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Host name: pop.mail.yahoo.com
User name: [email protected]
Password: password for yahoo account
Server port: 995
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SMTP: smtp.o2.co.uk (o2 is the name of my phone network)
Server port: 25
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Name: xyz
Address: [email protected]
Password: password for yahoo account
Description: Yahoo!
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Primary server: Yahoo! SMTP server
Server port: 465
I’ve tried using the same settings in my new iPhone5, but it doesn’t work. I can receive mail to both accounts, and can send from the Yahoo account, but I cannot send mail from the alias account. When I try, it displays the message: “Cannot send mail. A copy has been placed in your Outbox. The recipient ‘[email protected]’ was rejected by the server”.
I’ve tried to configure the POP alias account using combinations of ‘pop.mail.yahoo.com’, ‘pop.mail.yahoo.co.uk’, ‘apple.pop.mail.yahoo.co.uk’ and ‘apple.pop.mail.yahoo.com’, for the incoming host, and ‘smtp.o2.co.uk’, ‘smtp.mail.yahoo.com’, ‘smtp.mail.yahoo.co.uk’, ‘apple.smtp.mail.yahoo.com’ and ‘apple.smtp.mail.yahoo.co.uk’ for the outgoing mail server. None of these have worked.
I’ve also tried setting it up using IMAP instead of POP without success. I tried configuring it using combinations of ‘imap.mail.yahoo.com’, ‘apple.imap.mail.yahoo.com’, ‘imap.mail.yahoo.co.uk’ and ‘apple.imap.mail.yahoo.co.uk’ for the incoming mail server and ‘smtp.o2.co.uk’, ‘smtp.mail.yahoo.com’, ‘smtp.mail.yahoo.co.uk’, ‘apple.smtp.mail.yahoo.com’ and ‘apple.smtp.mail.yahoo.co.uk’ for the outgoing mail server.
Yahoo say that if I can't send Yahoo! Mail from my mail program, I may be accessing the Internet through an ISP that is blocking the SMTP port, and that if this is the case, I should try setting the SMTP port number to 587 when sending email via Yahoo!'s SMTP server. I don't think that this is the problem, but I tried it just to make sure - without success.
I’ve also heard that the problem might have something to do with the SPF settings of my alias domain provider. I’m not too sure exactly what SPF settings are, or how to change them, but from what I can gather it seems unlikely that this is the problem given that I was able to send mail from my alias account on my old iPhone3.
Any help much appreciated: how can I get my alias account to send emails in iPhone5 mail?
Many thanks,
Patrick

A new development: I've tried sending emails from the alias several times over the past 24 hours, but in general I've deleted them if they haven't sent within about half an hour.
However, one of the messages I left sitting in the outbox did send successfully in the end, but this took about an hour.
So: perhaps my problem is not in fact that I am completely unable to send mail from my alias, but that I can only do so intermittently and extremely slowly, and by ignoring the "cannot send" message.
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Critters222-
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Message was edited by: Fred*M.

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Hi,
I have an S5 that I use to receive email from my personal email account (supplied by Primelink). I can receive email fine, but can't send anything. My SMTP server is mail.wgtest.com using port 465. I am using K9 mail as my email app.
I was told by Primelink that it's a Verizon Wireless issue. Is there any way to respond to my emails from my phone? I can send via my hotmail account, but then my hotmail sent message folder gets filled up and the reply to address always shows up as my hotmail address, not the wgtest.com address.
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Can't Send Email from Iphone Using Pop Account

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