Can't SEND email - Outlook 2010 - Just moved from ...

I use an email address at my own domain, it's my business email.  The domain is managed by Eclipse Networking a firm in Exeter.
I moved to BT Infinity yesterday from Talk Talk.  Now I can only receive email, not send.  I use Outlook 2010.  I have changed the SMTP settings to those of BT  - mail.btinternet.com
And ticked for authentication
And chose SSL (like it says on the BT help webpage)
And specified port 465 (like it says on the BT help webpage)
And put in my MY BT user id and password
But it doesn't work
I spent an hour today talking to a BT teccie who used remote access to my computer to try himself.  Nothing doing.  He finally said BT SMTP only supports their own BT email addresses.
Can you help, what should I do next -  it would be much appreciated - I am pretty desperate and stressed - didn't sleep well last night as all this was on my mind as I have a business to run.
Thank you

I only have Outlook 2007 but it should be the same for 2010.
Go to File > Account settings > select the account > change > More settings > outgoing server.
click 'log on using' and then enter your full btinternet email address and password

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