Can't Send Email - Receiving Just Fine

I bought a new Mac G5 and am setting it up. I have a G4 with my mail accounts working just fine - sending and receiving. On my new G5 I can receive emails, but cannot send any. I've used Connection Doctor (in Mail) and the accounts pass all tests for incoming and outgoing servers. I have two accounts set up and get the same reults on both. When attempting to email I get the following:
"Cannot send message using the server outgoing.verizon.net:xxxxxxxxx.
The server response was: 5.7.1 Missing or literal domains not allowed
Use the pop-up menu below to try a different outgoing mail server. All messages will use this server until you quit Mail or change your network settings."
I have checked and rechecked for typos, but find none. All information is exactly the same as on my G4 which sends just fine.

Go to Settings => Mail,Contacts,Calenders => select the account and may have to click account again => should be viewing username and password, Scroll down and Select - Outgoing Server => Tap on Primary Server => try entering Username and Password in there even though it says optional...
Also try port 25 if that doesn't work and try toggling SSL on/off if that doesn't work.
iOS: Unable to send or receive email
http://support.apple.com/kb/TS3899
What settings do I need from my Email Service Provider?
http://support.apple.com/library/APPLE/APPLECARE_ALLGEOS/TS3899/My_Email_Setting s.pdf

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