Can't send emails from a btinternet address unless connected to a WiFi network

I am a UK user with an iPhone 5 and Vodafone as my ISP. After installing IOS 7 both gmail and btinternet addresses continued to work well until I upgraded to IOS 7.0.2 since when while I have been able to receive emails with a btinternet address I cannot send when not connected to a WiFi network and 3G makes no difference - gmail will still receive and send however.
Does anyone have a solution please?
Mike Searchfield

Really hard to diagnose without being there, but check with your friend that they don't have any softward filters on wireless router that block ports etc. If it's not your friends wireless, it could be something much more simple like needing to just restart your ipad to reset settings. Good Luck!

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Suddenly my outgoing emails have stopped working - Im on BTInternet. SMTP settings haven't changed, but nothing.
Ugh! Any ideas anyone?
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Spent two hours on the phone today with BT. They escaleted the problem to a specialist support desk, which we then had to agree to paying a £30 charge if they were able to fix the problem as they say that it is a problem with mac mail. (Which it isn't because it works fine using a different broadband connection, and we have three laptops in the house all with same problem!).
All three laptops have been working with out fault for the last four years and just before christmas they all stopped being able to send emails using hotmail. Obviously BT have changed something somewhere along the line.
The Specialist just changed our outgoing mail server to use BTs instead. (I have been using a different SMTP server anyway as a temporary fix since christmas) Whilst we are able to send emails, we are still unable to connect to hotmails SMTP server. Still had to pay the £30 though. As far as they are concerned that still counts as a fix. Another "solution" they gave me was to change the DNS address in system preferences- Not Ideal as everytime you connect your laptop to a new network you will have to reset them.An absolute joke.
Their direct number is 08000 321 118 if you need them to talk you through it. Best to have your bank card to hand.
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OT

On 3G we cannot send emails from either our iPhones or iPad and this also happens with some WiFi connections but not all. Yet we can always send emails from our Hotmail Email account. What is causing this and what do we need to do to resolve it?

On 3G we cannot send Business emails from either our iPhones or Ipad and this also happens with some WiFi connections but not all. Yet we can always send emails from our Hotmail Account using both 3G and WiFi.
We bought the iPhones and Ipad so that we could send emails while we are out of the Office, but we are not able to do this unless we can find a WiFi connection. Incoming emails are fine. We use IMAP, for Business emails just incase this is relevant and I know that Hotmail is POP3.
Our technical IT knowledge is not great, so we look forward to your suggestions as to how to resolve this.

Contact whomever supports the email account and get the correct Outgoing email server settings from them.

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Try closing the Mail app completely and see if it works properly when you re-open it : from the home screen (i.e. not with the Mail app 'open' on-screen) double-click the home button to bring up the taskbar, then press and hold any of the apps on the taskbar for a couple of seconds or so until they start shaking, then press the '-' in the top left of the Mail app to close it, and touch any part of the screen above the taskbar so as to stop the shaking and close the taskbar.
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https://discussions.apple.com/message/21173608#21173608

Can't send emails from a btinternet address unless connected to a WiFi network

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