Can't send mail after mavericks upgrade

MacPro user (mid2010)
I am using a third party email address and am currently with O2 Broadband. Since upgrading to Mavericks, I am unable to send emails using the Mail app.
My outgoing mail server is: relay.o2broadband.co.uk
And I'm using the default ports.
I am aware that O2 Broadband customers are being moved over to Sky but my account is still with O2 right now.
I can send mail just fine on my Laptop which is still running OSX 10.7 so I'm fairly convinced this issue has something to do with Mavericks.
Anyone else suffering the same issues? I'd really appreciate any advice anyone can offer.

Before I finally got it working (and I'm not even sure how), I tried PostBox and Airmail and had the exact same outgoing mail problem.  So it appears that there is something more fundamental in the OS happening.  From a couple of these other threads (and I read them all out of desperation...) it sounds like there's some funky sync thing that has to happen with certain host email configs, and Mavericks doesn't do it perfectly at first.  Somehow (yes I'm showing my tech ignorance) some configs require a login to IMAP/POP3 immediately before allowing access to the SMTP to send, presumably in another attempt to block sending spam by third parties.  The timing of the dual login has to be tighter in Mavericks?  But this aligns with my experience in that an account (I had three that had problems) would receive an email and them boom the SMTP would work.  So I tried sending an email from my phone to be received on the problem account and tried to send from that account right at the same time, and somehow it worked.  Once it worked, it stayed working.  However I still cannot get SSL (port 465) to work - I had to change everything to non-SSL on port 25 or 26.  Even though my iPhone and iPad will work...

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        NSFilePath = "/Users/kylie/Library/Application Support/AddressBook/MailRecents-v4.abcdmr";
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