Can't send mail--all suggestions tried!

Greetings,
I can see by many posts that this is a common problem with many good hints, but I'm still baffled.
I can get mail, but I cannot send mail (except for sending myself an email; that works fine). (My ISP, RoadRunner, says I'm configured perfectly.)
The error message I get is: "Sending the message content to the server failed."
To fix the issue, here's what I've done: powered down the G4, router and AirPort. Rebooted to no effect. Checked the Mail function on my laptop using AirPort: works perfectly (though it is running Panther, not Tiger). My built-in Mac firewall is switched off. I have installed no security updates of late--though one is pending.
I'd sure prefer not to reinstall Mac Mail. Any thoughts? Thanks!
Tim
PowerMac G4 dual   Mac OS X (10.4)  

Tim,
Mostly involved in some projects away from the computer, and a little hit or miss on time to research. My initial google using "smtp authentication roadrunner" turned up some stuff about the brand of modem. You might try that same search, but add "Asante" to the search argument.
However, the fact that I understand your laptop running Panther to work (via Airport), and the error message you cited I thought that you might be trying to authenticate. Also, the laptop and Airport success does not point so much to the modem or any device.
I may need to better understand your network, which seems to be two Macs connected via modem/router, but at least one (the laptop) wirelessly via Airport Express(?) which is presumedly cabled to the router. How is the second Mac, running Tiger, connected?
While I cannot yet conclude anything, without further info, I am interested in the role MTU (maximum transmission unit) might have on your reports. See:
http://docs.info.apple.com/article.html?artnum=303192
If the Tiger Mac is cabled to the router, rather than wireless, try reducing the MTU value, starting at 1492, and then downward. If could simply be the packet transmission speed the Tiger Mac is trying to use, prevent delivery of the message content?
Ernie

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