Can´t send mail with 3g

I have problem with my outgoing server.
I have 3 outgoing servers:
Primary: mail1.comhem.se
Secundary servers: mailout.telia.com
smtprelay1.telia.com
It works well sending mails with Wifi but as soon it goes to 3g it doesn´t work any longer, and these messages pops up saying that address is not valid or connection timeout.
But as soon as it get back to Wifi, swoosch and away it goes!
What can be wrong? Have I missed something in the setup?
Receiving mail are no problem with 3g.

When I used mobile-smtp.roadrunner.com it failed to send. It put the message in the Outbox and said the sender address [email protected] was rejected by the server.
I think that's because my roadrunner email is on the cinci.rr.com server and not the roadrunner.com server
I had it set up:
mobile-smtp.roadrunner.com
SSL off
Authentication: Password checked
server port 587 <-----note it wouldn't accept 597 here. The 587 port is there in all mail servers once they verify
In order for my mail to work with AT&T's network, I had to make their server the Primary:
Primary Server: cwmx.com
SSL off
Server Port 25
Authentication" Password checked
I've tried all these below as Secondary servers
smtp-server.cinci.rr.com
SSL off
Authentication: Password checked
server port 587
smtp-server.roadrunner.com
SSL off
Authentication: Password checked
server port 587
mobile-smtp.roadrunner.com
SSL off
Authentication: Password checked
server port 587

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