Can't send mail with WiFi on-ok with only 3G running

Using AT&T 3G network, Time Warner RoadRunner via Airport Express. I can download ok with both wifi and 3G running. But when I try to send, the msg just sits in th Outbox. IPhone 4 with latest OS. I'm using MS Entourage on my iMac as POP server.  I can access mail fine on the phone. Everything works except the Send hangs in the Outbox until I turn WiFi on the phone to OFF. A hung message will send moments after turning the wifi off

When I used  mobile-smtp.roadrunner.com   it failed to send. It put the message in the Outbox and said the sender address [email protected] was rejected by the server.
I think that's because my roadrunner email is on the cinci.rr.com server and not the roadrunner.com server
I had it set up:
mobile-smtp.roadrunner.com
SSL off
Authentication: Password checked
server port 587        <-----note it wouldn't accept 597 here. The 587 port is there in all mail servers once they verify
In order for my mail to work with AT&T's network, I had to make their server the Primary:
Primary Server: cwmx.com
SSL off
Server Port 25
Authentication" Password checked
I've tried all these below as Secondary servers
smtp-server.cinci.rr.com
SSL off
Authentication: Password checked
server port 587
smtp-server.roadrunner.com
SSL off
Authentication: Password checked
server port 587
mobile-smtp.roadrunner.com
SSL off
Authentication: Password checked
server port 587

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