Can't send mails (POP account/SMTP)

Okay, this issue has been posted before, but none of the difficulties or possible solutions described seemed to match my problem, which is:
When I click the "send" button in Mail, it simply does *nothing at all*. It doesn't even seem to try to do anything, let alone give me an error message.
I used to have an iBook with OS X 10.2, and Mail has always worked perfectly fine on that system. Now I just bought a new iBook with Tiger installed. I first updated to 10.4.6, then transferred all my data, including my mail settings and mailboxes, to the new computer, with the result that I can receive mail, but I can't send e-mails. I tried deleting my account and creating a new one, but that didn't change anything. I can send e-mails through my provider's webmail system, so the SMTP server isn't broken down; anyway, my husband is using the same server, and he can send mails, so I guess it's somehow an issue with my computer and not with the provider. My account settings are definitely correct. I can "ping" the mail server. I tried deactivating my firewall, but that wasn't the solution either.
What else could I try? My outgoing mail server is an ordinary port 25 password-protected SMTP server. I strongly suspect that the problem is with 10.4.6, but I'm not exactly keen on the hassle of downgrading my system back to 10.4.5 or whatever... Or is there an easy way to do that?
Any other ideas? I'd be really grateful. Not being able to send mails *****.
-Johanna

Hi Johanna,
Have you tried the Activity Viewer? (Window > Activity Viewer in the menu.) Try sending an email, and see if any error message appears in the Activity Viewer window after you click "Send".
Matt

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