Can't sent email with Mail.app

When attempting to send outgoing mail from Mail I get this warning.
"The attempt to read data from the server “mailhub.une.edu.au” failed.
You can try to send using a different server. All messages will use this server until you quit or change your network settings."
I've tryed to solve this by deleting all the server and email info, and re entering it. I had thought that that may fix the situation (I had also at various time switched authentication on and off and changed the port from 25 to 587) But I still am getting a failure message as shown above. I have also put the outgoing mail as the networs SMTP serve.
Can someone help me. It s a pain to have to go to the .mac site and log in each time I want to send my emails.

No, we cannot eliminate all those things, not by a long shot!
A very important question I asked was: In Mail, is your Username appended to the name of the SMTP, or not? Please answer. You should also ask your ISP if the form of Authentication for their SMTP will result in the name of the SMTP being appended with your Username. Have you found any support pages that show this for any other mail client, on any other computer platform?
It does not matter what you do with regard to any other SMTP server, until you determine how to make the one with the ISP work with Mail, or with Th'bird, because any third party SMTP must relay to that of the ISP, and if it does work the one for your Webhost will also not work!
Ernie

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