Cannot edit outgoing SMTP server list in mail.app

Did a fresh install of Snow Leopard on a new 13" Macbook Pro unibody and was trying to add an IMAP email account. After failing to connect, I was trying to specify the outgoing port and realized that I could not edit the outgoing SMTP server list.
Steps to reproduce error:
1. Open mail.app
2. Go to Mail > Preferences
3. Select "Accounts" tab and select any mail account
4. Select "Account Information" tab and click Outgoing Mail Server (SMTP) drop down menu
5. Select "Edit SMTP Server List..."
After that point the instead of opening the list of servers with their settings, it simply returns to the "Account Information" screen. I'm a bit confused because I've never had this happen before in any other version of mail app. I cannot edit or delete any outgoing mail server accounts because of this. Any help will be much appreciated. Thank you for your time and consideration.

This should not happen. Had you migrated back to the fresh install the Mail folder in User-Library? Or is this a clean setup? I would go to User-Library-Preferences, and drag the com.apple.mail.plist to the trash, then open Mail and try again.

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