Cannot send email from iPhone5--calendar syncing issues also

I have an iPhone 5 and am not currently using iCloud. I have 3 email accounts.
The first is a yahoo email account--and it both receives & sends emails just fine.
I use Outlook for the other two email accounts (one is an IMAP and the other is a POP). Both receive email, but I cannot send out emails from my iPhone. When I try to send an email from either account, I get this message:
"A copy has been placed in your Outbox. The sender address "[address I used]" was rejected by the server.
Also, I don't know if it is related, but my iPhone calendar isn't syncing with Outlook. I add an appointment on my iPhone or in Outlook, and it won't appear in the other location (Outlook/iPhone).
Thanks for your help.

Check your settings, maybe the mail index is at fault.
Setup Wizard and troubleshooting tips:
http://www.apple.com/support/mail
Also has a link to Mail community section.

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Cannot send email from iPhone5--calendar syncing issues also

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