Cannot send emails from mac email address

Over the past 24hrs I am unable to send emails from my ibook and sporadically from my iphone. Please advice what the settings should be for SMTP and port. I think this might be the problem but I am unsure. I have a mac email address. I can send emails from my icloud account. Any help would be appreciated. Thanks

Wow, after research I can't believe what a problem BT is!???
This post by vanessa seems to have gelped many that could not send...
Just set up my macmail with the help of the BT guys after a year of struggling! Hopefully this could work for others for whom the emails will receive but NOT send....
Set up your 3rd party domain names via the mail relay system and confirmed via BT. Then try these settings.....
In your @btconnect.com email set its up using these:
incoming mail server: pop3.btconnect.com
username: the bt email
password: the bt email password you supplied
outgoing mail: we'll come to this!
on the drop down box next to Outgong mail server (SMTP) select 'edit SMTP server list'
press '+'  button and add these details....
In the Account information tab:
Description: mail.btconnect.com
Server Name: mail.btconnect.com
In the advanced tab:
Select 'Use default ports'
Authentication: Password
username: the bt email
password: the bt email password you supplied
NOW The next bit, the 'second' server....
press '+' fro a new server add these details....
In the Account information tab:
Description: second server (or any name you want)
Server Name: mail.btconnect.com
In the advanced tab:
Select 'Use default ports'
Authentication: NONE!
Now on all your email addresses back in the accounts section, set the SMTP server to 'second server' (or whater you hae called it) NOT mail.btconnect.com and select Use only this server.
http://business.forums.bt.com/t5/Email/How-to-Set-Up-Mac-Mail-OSX-Lion-inc-mail- relay-Message/td-p/30323

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