Cannot send mail via wi-fi at work

mail works perfectly at home (d-link wifi time-warner cable modem). at work, receives normally but will not allow me to send. administrator says it's my macbook pro to blame- nothing from their end to stop mail from sending. any ideas?

Actually, a lot of ISPs have for years and years only allowed use of their SMTP servers for mail originating from their own IP address pool. It really has nothing to do with spam - ISPs only want to pay for processing SMTP services from their own paying customers. So IPs outside of the ISPs domain(s) are automatically blocked. As I say, this has been common among many ISPs for a very long time.
Does the ISP use authenticated SMTP? If so, make sure you have your mail app set to use your userid and password when sending mail. Again, many ISPs will allow authenticated SMTP requests from any IP address (while when you are at home, it may not be necessary, as your IP address allows for unauthenticated SMTP access).
Alternatively, as suggested, just setup and use your employer's SMTP server when at work.

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