Color issues in Photoshop CS6

Question

A few days ago my Photoshop installation began muting all of the colors. Nothing I've found has been able to change it. Color Settings are set to North America General Purpose 2, I even tried deleting Photoshop's preferences file and letting it recreate it to return everything to default, no change. Here's a perfect example of what I'm talking about http://i.imgur.com/EpFgI.png
On the right is a website pulled up within Chrome. On the left is a screenshot taken (via Print Screen) of that exact same web page and then pasted into a default web RGB settings file. It's easy to tell the difference when you look at the blues. This is happening to everything I load in photoshop, color profiles or settings don't make any difference, and no other applications have this problem (including other Adobe applications). Any ideas?
If it matters, I'm running Windows 8 with 2x AMD 6950's in Crossfire.

Answer 1

Thanks for helping. So I downloaded the Whacked RGB file and opened it in photoshop, I get this message http://i.imgur.com/xQ8VV.png and the file looks perfectly normal if I open it with the embedded profile or if I convert it to the working space. Discarding the embedded profile makes it blue. Does this help at all? The link you sent says "In conclusion, if your setup is displaying the WhackedRGB file at least okay, then the problem points to your "problem" files — they either have profile issues or the actual problems Photoshop is showing you. Period." when this is the case.
I also found another quirk while messing with this, the color actually looks fine in my other monitors. If I drag the photoshop window over to my primary monitor, the colors stays perfectly fine until I actually drag my cursor over the file, then it changes. I recorded a screenr to showcase this http://www.screenr.com/FFC7 so you can watch it in real time, just keep your eyes on the blue. It must be a monitor profile issue specifically with photoshop, I'm just not sure how to fix it.