Disks won't unmount

Hello,
I have an old imac, that is running OS 10.6.5;
As of today I cannot get it to unmount any disks:
USB drives
CD's
External hard drives (Both USB and Firewire)
I have tried to repair permissions and repair the disk (Disk Utilities) both cases give a clean bill of health.
The only thing that I have done recently was to perform the most recent update yesterday. Could this be connected?

I'm not sure what's going on to be honest. I Googled the error message however unfortunately while I got hits on it I didn't come up with any replies. If you're covered by AppleCare I'd recommend contact them, you will probably need escalation until you get to someone knowledgeable about Unix. If you don't have AppleCare well you will either have pay for the incident or get support on the forum.
I didn't know. I'm assuming that when you do the SMC reset you are unplugging EVERYTHING, holding down the power button for 5-15 seconds and then powering on with only the keyboard and mouse plugged in. Next plug in one drive at a time and test it. Also if you are using a hub of any type eliminate that from the equation until you can find what is causing the error.
If the problem occurs create another user account and leave it absolutely pristine, don't add any applications, don't change any setting nothing!!! Then try that account, if it works then you know it's not a hardware issue and it's a software issue localized to the user account with the problem.

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