Email account won't send from iphone

I just switched from a blackberry to iphone 4. I have set up all of my email accounts but my work account won't send emails to any accounts that are not from our server. I never had this problem with my blackberry so I know it can be done. The message always says "email address rejected by server". Anyone else have this problem?

hi there
Sorry no answer, just to say i am getting the same message when trying to send mail from my yahoo account. I have a Microsoft exchange account for work which seems to be fine.
Glad i am not alone!
Cheers

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