Email shows wrong Sent From account

No matter what I do, the default email "return" address won't show my main account, but only the one that is "second in line".
How do I permantly set the default return address?
Having to do each one manually is a pain in the butt.
It has worked fine until just recently, then it was occasional, now every single one shows the wrong account.
What's up, I didn't change anything.....
eMac   Mac OS X (10.3.9)  

Is there a way to add this automatically?
For a semi-permanent change, the Sending Server is named as "OutGoing Mail Server SMTP" on the Preference pane for each Mail Account.
To change its specifics, move the mouse cursor over it and choose "Edit SMTP Server List" from the drop-down Menu. Then choose the SMTP Server you wish to inspect/change and its information will be shown. If using similar ones for two different email accounts, change the description field, e.g., change "gmail" to "gmail (work)".

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    Command: Mail
    Path: /Applications/Mail.app/Contents/MacOS/Mail
    Parent: WindowServer [56]
    Version: 2.1 (752)
    Build Version: 1
    Project Name: MailViewer
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