"empty file" error in Mail from PDF attachments created on a PC

Hi all,
We have an odd situation where a particular PC user seems to be unable to send MacMail-compatible .pdf files.
When she sends the files, Mail gives the following error upon trying to open them:
"The file xxxxx could not be opened because it is empty."
This only happens in Mac Mail.
The files open fine in both our Zimbra webmail system, and Thunderbird.
Additionally, when I hover my cursor over the attachment icon in Mac Mail, I get the following popup:
"status: not yet downloaded"
I've searched in vain for info on both of these messages.
Any ideas?
Thanks!
OS: 10.6.7
Model: 3Ghz Core i3 iMac

Hi Paul,
Does this Mac have Sophos installed? If so, see the topic at the link below:
http://discussions.apple.com/message.jspa?messageID=13387558#13387558
Note the need to also remove the com.apple.mail.plist, and instructions for doing that.
Ernie

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