Error:Message could not be delivered will remain in Outbox

The error message further states that "The server*** cannot be contacted on port 25" This happens when the computer is sleeping and an alarm is sent from iCal. On my older computer, the mail would open automatically and display the alarm message as soon as I opened the computer. No it opens but gives the above error message. Do I need to change a setting of some kind?
Macbook   Mac OS X (10.4.8)  

Thanks for responding
Is this email account and SMTP server provided by your ISP used for connecting to the internet or an email account provider only that is not associated with your ISP?
This email account is associated with my ISP.
I have no other problems forward, sending or receiving mail on this account. The only problem remains when iCal sends an alarm and my computer is in"sleep" mode. Then the message stays in my Outbox and won't be delivered.

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