Error when trying to save a file

I get this error when trying to save any file (newly created or not) word document in MS word 2010:"You are attempting to save a file type (plain text files) that has been blocked by your File Block settings in the Trust Center".
I followed the directions given by the Microsoft Knowledge Base article 922850, but I am still having this issue. I can still save files as PDF but not in any kind of word format.
I also tried opening another file copy and pasting under a different name and it doesn't help.
Please Help.
Bruce

Hi,
Please try the following methods:
Using Administrative Template files and the Office Customization Tool to disable the restriction
Use a trusted location, or create an exempt location
Quote from:
http://support.microsoft.com/kb/922849/en-us
Regards,
George Zhao
TechNet Community Support

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I also tried the alt/ctrl/shift buttons when clicking Editor in the Photoshop welcome screen. It did ask if I wanted to reset the preferences. I chose yes. I still get the same error message when trying to save for web.
Below....showing I don't have a "save for web" folder on my C drive.
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