Everything freezes when printing

For some reason it is taking a very long time to print from any program and everything becomes unresponsive until it does. It was taking about five minutes for plain text. I installed Print therapy and ran various clean ups and cut it down to 1-2 minutes. I checked the console and realized I get several error messages when I print:
Dec 27 14:53:17 admins-powermac-g5 kernel[0]: disk0s3: I/O error.
Dec 27 14:53:17 admins-powermac-g5 kernel[0]:
Dec 27 14:53:24: --- last message repeated 1 time ---
Dec 27 14:53:24 admins-powermac-g5 kernel[0]: disk0s3: I/O error.
Dec 27 14:53:24 admins-powermac-g5 kernel[0]:
Dec 27 14:53:30: --- last message repeated 1 time ---
Dec 27 14:53:30 admins-powermac-g5 kernel[0]: disk0s3: I/O error.
Dec 27 14:53:31 admins-powermac-g5 kernel[0]:
Dec 27 14:53:31: --- last message repeated 1 time ---
Dec 27 14:53:31 admins-powermac-g5 com.apple.service_helper[1341]: launchctl: Error unloading: com.apple.efax
Dec 27 14:53:31 admins-powermac-g5 [0x0-0x55055].com.apple.systempreferences[1336]: No matching processes were found
Dec 27 14:53:44 admins-powermac-g5 kernel[0]: disk0s3: I/O error.
Dec 27 14:53:44 admins-powermac-g5 kernel[0]:
Dec 27 14:54:14: --- last message repeated 1 time ---
Dec 27 14:54:37 admins-powermac-g5 kernel[0]: disk0s3: I/O error.
Dec 27 14:54:38 admins-powermac-g5 kernel[0]:
Dec 27 14:55:08: --- last message repeated 1 time ---
I've tried deleting all the print plist files, repairing permissions, deleting then reinstalling the driver from the samsung website. I dont know what else to do. My printer is connected via usb, ML-2510. Please help.

i was afraid of that, i will check the smart system thanks. Im not experiencing any slow down or issues with any other program. But this may be related. When i tried to back up my system using CCC, i got the message below. so im not sure if it succeeded or not. I chose to be able to boot from my backup but it doesn't work when i try.
21:52:25 Building a list of items to be considered for backup
22:05:29 Preparing to copy, total items to consider: 1004472
22:05:29 Build time: 784.046
22:05:48 Comparing selected items on the source and target...
23:06:35 Detected input/output error
23:06:35 rsync: read errors mapping "/private/var/log/cups/error_log": Input/output error (5)
23:08:40 Detected input/output error
23:08:41 rsync: read errors mapping "/private/var/log/cups/error_log": Input/output error (5)
23:08:41 ERROR: private/var/log/cups/error_log failed verification -- update discarded. (51)
23:09:29 rsync exited with status 23
23:09:29 CCC Synchronization Engine exited with a non-zero exit status: 23. (51)
23:09:30 CCC Synchronization Engine: CCC detected "Input/output" errors during the clone., Error code: 54
23:09:30 Sync Engine warnings: (
"rsync: read errors mapping \"/private/var/log/cups/error_log\": Input/output error (5)",
"rsync: read errors mapping \"/private/var/log/cups/error_log\": Input/output error (5)",
"ERROR: private/var/log/cups/error_log failed verification -- update discarded.",
"rsync error: some files/attrs were not transferred (see previous errors) (code 23) at /Volumes/Home/Users/bombich/Development/Bombich_Software/rsync/rsync-3.0.6/main .c(1044) [sender=3.0.6]"

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