Expense charge account not defaulting

Hi All,
One of the user getting the following error,
Row 1 Charge Account - Charge account is invalid. (Program error: An error has occurred while looking up a flexfield segment combination. Please inform your support representative that: The FND_FLEX_SERVER validation function has encountered a null or negative combination ID () while trying to look up the segment values for this combination. This may indicate an invalid entry in the unique ID column of the combinations table.).
Issue is user tries to create an Req and adds to his cart,when he tries to checkout he gets this error.But the employee has been setup with the expense account in the HRMS assignment tab and an expense rule set is also been defined for that category which will replace the default account.But none of this happens,when whe views the account details in the line both the account and dept segment is empty which causes the above error.
I really need help as iam not able to find solutions in metalink.
Thanks,
Vijay

Don't know much about this......but is there an error number?
I found a bunch of links in the metalink....don't know which one would be applicable in this case.
Cheers,
Chiru

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