External Harddrive showing Empty but isn't

Before I went to bed last night, I started transferring some of my iPhoto libraries from my MacBook Pro (Oct '09) to an external hard drive. When I woke up this morning to make sure everything had been copied properly, I found the drive unresponsive and I was unable to eject it.
I reboot my laptop and after plugging in my drive, I was horrified to find that the drive was no longer recognizable. I believe the data is still on the drive because it is a 400Gb drive and it says there are only 262GB available.
This drive contains all of my family photos that have been organized. Luckily, I have most (if not all) of the photos backed up on either CD, DVD or another drive. However, they are not organized and I really don't want to have to repeat the organization process which took quite a while...
Does anyone have any ideas how to recover the information on the drive? Since it isn't show any folders at all, I am not sure how to proceed.

I reboot and connected to the first drive (400GB WD My Book) to be sure that absolutely no applications were running. When I tried to copy files from one drive to the other, I got the following error:
The operation can’t be completed because the item “Ellas iPhoto Library” is in use.
If I try to copy an iPhoto library file from the second drive (640GB WD MyBook) to a brand new directory on the same drive, I get a file exists error:
The operation can’t be completed because an item with the name “iPhoto Library - FULL” already exists.
It seems to be hit or miss on copying a file to a new location on drive 2 (640GB) and drive 1 (400GB) is pretty much inaccessible. On the new connection, running disk utility produces a new message:
*Verify and Repair volume “WD - 400GB”*
*Error: Could not unmount disk*
Any operations on the 400GB drive cannot be completed because the "files are in use". Nothing other than FireFox is Running...

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