First-time user of IPod Shuffle, my husand has an IPod Touch and has hundreds of songs already on his ITunes account. If Is it possible to have two ITunes accounts so his music is not automatically loaded onto my new Shuffle?

Just bought an IPod Shuffle; my husband has an IPod Touch and has hundreds of songs on his ITunes account.  Is it possible to have two different accounts on the same computer to prevent his music from being loaded onto my Shuffle?

When you say "iTunes account," I think you mean iTunes library.  An iTunes "account" is what you use to sign in to the iTunes Store (your Apple ID) and purchase songs (and other media).  The iTunes library is what you have on your computer, with your songs and playlists.  That is what you use for syncing iPods.
You can have a separate iTunes library.  If you create a new user account on your computer (using Windows) and log in to that user account, iTunes will create a new iTunes library for that account.  In fact, Windows will keep ALL of your documents separate, as if you are using a separate computer.  That is probably the best way to keep your songs in a different iTunes library.
You can also create a separate iTunes library in the same Windows user account, if you use this procedure to switch between iTunes libraries
http://support.apple.com/kb/ht1589
Also, you can use the same iTunes library, and decide what songs you want put on the shuffle.  iTunes does not automatically put songs on the shuffle, unless you tell it to do so.  This document explains how to load content on shuffles
http://support.apple.com/kb/ht1719
NOTE:  If the iTunes sidebar (along left side of window) is not visible, from the menu bar, under View, select Show Sidebar.  When connected, your shuffle appears in the sidebar, under DEVICES.
FYI - There is a link to the shuffle user manual on this support web page for the shuffle
http://www.apple.com/support/ipodshuffle/

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