Getting error when attempting to sync with iPhoto

I just purchased a new iPod Classic, when I tried to sync with iPhoto I get the error message "Unknown Error -50" or something close to this, I'm sure the error number is -50. Anyone have any ideas what the problem is? iPhoto works fine.

OK, I've figured out what is happening. After researching the XML file information available on the web, I found out that iPhoto doesn't actually use this file. It simply creates the XML file for other programs to use (like iTunes). The bottom line here is that I would run the xmllint utility, test that iPhoto still works (causing the bad data to be put back) and then running iTunes, at this time it still failed because iPhoto had updated the XML file with the bad data.
Running xmllint and fixing the line that it pointed out and then running iTunes allowed me to sync my photos to my iPod. For me it's a bad comment there was some unprintable character in the file that was causing the problem. The xmllint utility correctly identified the bad line and bbedit let me fix the issue (there is a bbedit setting that shows invisible characters). I haven't run iPhoto and attempted to fix the bad comment yet, I'll report on my efforts later.
Thanks to all for you help.

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