Help!!  "This does not appear to be a valid Podcast URL" -- but it is!

I'm having trouble subscribing to the Vatican Radio podcast (English version). I recently moved to a new computer and resubscribed to all my podcasts. This is the only one that won't work for me.
I've contacted the Radio Vatican webmaster and he's confirmed I'm using the right URL - www.radiovaticana.org/rss/inglese.xml
But when I subscribe to it through either the iTunes Music Store or the iTunes "Advanced" menu I get the reply - "http:www.radiovaticana.org/rss/inglese.xml does not appear to be a valid Podcast URL. Please check that you have entered the correct URL and try again."
I'm able to download individual programs through the Music Store, but it won't take a subscription for some reason.
Anyone have any ideas? I've never faced this before.
FYi I'm using the latest version of iTunes on a MacBook with version 10.4.7.
MacBook   Mac OS X (10.4.7)  

Plug that URL into a feed checker site, and you get a "mass" of errors. Pass that along to them, they need to fix these errors.

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