How do I delete podcasts I have listened to from latest version of iTunes?

I am not able to keep up with the new versions of iTunes and IPod (now on iOS 6.0.1). It seems you have to completely re-learn things almost every month!
I download podcasts from a lot of sources, but virually never direct from iTunes (I find the search bar in iTunes almost useless and can rarely find what I want, whereas I know the home sites of the podcasts I do want, and want to manage all the downloads manually).
I listen to them and afterwards manually delete them directly on my iPod.
Before the latest version, I never used to sync my iPod and so it didn;t really matter to me what was in my iTunes library.
I now find it very difficult to manage the iPod manually (transferring things individually into iTunes and then to iPod, so yesterday I (accidentally) deleted everything in iTunes and iPod and started again. I now find that I cannot delete things from iTines and am scared that when I next sync my iPod, all the podcasts I have already listened to and deleted directly on the iPod will be re-loaded into the iPod.
Please could someone help me?
In an ideal world, without losing what I have re-loaded into the iPod I would go back to the previous version of ITunes and to the pre- latest update version of software I had on my iPod as I learnt how to do things undr those conditions!
Many thanks, and with apologies for being too old and tech illiterate to keep up with these constant changes.........
tks,
Nick

Have you looked at chapter 31 of Users Guide:
iPod touch User Guide iOS 6

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