How do I fix that at startup, restart Mavericks 10.9.2 always opens the system preference window?

How do I fix that at startup, restart Mavericks 10.9.2 always opens the system preference window?
It is not listed in Login items. I tried all the usual fixes plus Diskwarrior rebuild.
                                                                                                                                W.W.

I suggest deleting the Canon Network Scanner from Login Items to determine if that is the cause. Not knowing exactly what it does, I suspect it is intended to monitor the printer's supply levels all the time. It's not necessary to do that. You can always determine the printer's ink supply level every time you print something, when its Print dialog appears. You can also check its supply levels by opening System Preferences on your own, and selecting Printers & Scanners.
Bear in mind Login Items is simply a convenience that loads the programs you specify every time you log in. That feature is less important as it had been in the past since Mavericks will re-open everything that was open when you last logged out, if you select this checkbox:
If you want to add the Adobe programs to Login Items again, search for them using Spotlight. The Adobe programs themselves should not be causing this behavior.

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