HT1338 this is the message I am getting:  The application "Microsoft Word" can't be opened.

I am unable to open my documents... "The application "Microsoft Word" can't be opened.  What is going on?

Unfortunately you got caught up in the minor miracle of Rosetta.  Originally licensed by Apple when it migrated from the PowerPC CPU platform that it had used from the mid-1990's until the Intel CPU platform in 2006, Rosetta allowed Mac users to continue to use their library of PPC software transparently in emulation.
However, Apple's license to continue to use this technology expired with new releases of OS X commencing with Lion (and now Mountain Lion).  While educational efforts have been made over the last 6 years, the fact is that Rosetta was SO successful that many users were caught unaware UNTIL they upgraded to Lion or Mountain Lion.
Workarounds:
1. If your Mac will support it, revert back to your older OS X;
2.  If your Mac will support it, either partition your hard drive or add an external hard drive and install Snow Leopard (with Rosetta) to allow for a "dual-boot" system;
3.  Upgrade your PowerPC software or use an alternative programs; or
4.  The solution I use: Install Snow Leopard (and Rosetta) into Parallels 7 or 8:
                              [click on image to enlarge]
Full Snow Leopard installation instructions here:
http://forums.macrumors.com/showthread.php?t=1365439
NOTE: STEP ONE of the instructions must be completed on a Snow Leopard or Lion Mac and the resulting modified Snow Leopard.cdr install file can then be moved over to your Mountain Lion Mac for completion of the remaining steps.

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