I bought a song on itunes on my mac yesterday and it won't play on my iPhone

I purchased a track on iTunes via my mac yesterday and it will not play on my iPhone 6. In fact, it doesn't even show up in my music library on the phone when I sync it with my iTunes, yet everything else is fine. Any help would be great..

Hello there, abafc.
It sounds like you may want to setup Automatic Downloads for your purchases to download on your iOS device as well. The following Knowledge Base article offers the steps on how to turn that feature on:
Enable Automatic Downloads
http://support.apple.com/kb/ht4539
Turn on Automatic Downloads on your iPhone, iPad, or iPod touch
Tap Settings > iTunes & App Store.
Sign in with your Apple ID if necessary.
Tap the content that you want to automatically download. If iBooks isn't listed, you need to download iBooksfrom the App Store.
You can turn Automatic Downloads on or off over your cellular network on an iPhone or iPad Wi-Fi + 3G. Go to Settings > Store and turn Cellular Data on or off. Cellular Data downloads are limited to a file size of 50 MB or smaller.
Additionally you can try downloading the content to your device using these steps as well:
Download past purchases
http://support.apple.com/kb/ht2519
Music
Tap Settings > Music and make sure Show All Music is on.
Tap the Music app.
Find the item that you want to download.
Tap the Download  icon.
Thanks for reaching out to Apple Support Communities.
Cheers,
Pedro.

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