I can receive e-mails, but can't send them from external account

I have my school e-mail account attached to my iPhone. I can receive e-mails without a problem, but whenever I try to send e-mail to someone outside the .edu server, I receive the error message: "The server rejected one of the recipient's addresses. The message has been placed in your outbox." How can I fix this problem? Thank you for your help!

This indicates the account's SMTP server is not authenticated.
Most, if not all internet service providers block the use of SMTP servers that are outside of the ISP's network or not provided by the ISP being used for your internet connection at the time unless the SMTP server is authenticated. When connected to a cell phone carrier's cellular network for internet access is no exception. Does this occur when connected to the school's wi-fi network in addition when connected to AT&T's cellular network?

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