I can't create an email account in Outlook 2013 for my exchange server

Have tried many things on this issue.
I have a new tablet PC running Windows 8. I am able to connect to my Exchange Server account using Windows 8 Mail, no problem but when I have tried to set up an account for Outlook 2013 to connect to the same Exchange Server using exactly the same login
information I cannot get it to connect. I simply get the message that the Exchange Server is unavailable.
I've been able to connect a variety of other devices to the same Exchange Server account without any problem - iPhones, Windows Phone, iPads, etc, etc all without problem. It's just this device and Outlook 2013 seems to be the issue. From checking various
forums seems this is not an isolated issue but I've not been able to find a useful solution so far. Have deleted the user profiles and .ost files, switched off caching etc, all to no avail.
One key difference between the account information required by Windows Mail and Outlook is that in the Windows Mail system I am prompted to enter my domain information. I know this is critical from the information provided to me by our network administration
team but there is nowhere in the Outlook account setup process where I can enter my domain info.
Closest I've been able to get to success is to use the manual account creation process and select the Exchange ActiveSync option - this gets me to the point where I'm prompted for my username and password info but it fails at this step because I am connected
to a local domain (the domain account for the PC) and my user name and password are not accepted. There is nowhere in this login process that I can find where I can enter the correct domain info.
Any ideas on a solution would be very much appreciated - I use Outlook extensively in my work and whilst the Windows 8 Mail system is good, it doesn't have the level of functionality I need.
Many thanks
Wayne.

Have managed to solve this with your help Martina regarding using the domain\username combination.
Here's the solution in detail in case anyone else is having similar problems.
From control panels - select the User Accounts and Family Safety item, then the Mail (Microsoft Outlook 2013) item and then the Email Accounts option.
Select the Email tab and click 'New... button to create a new email account
Choose the standard Email account option in the following form. (Not the 'Manual' option'
Enter your Exchange account details - no alterations necessary here. just your standard details.
As the account verification proceeds you are prompted to again enter your username and password details. In this form, instead of using the top option with your username already populated, click the lower 'Other user' option and enter your domain\username
details. This changes the domain. Enter your password as usual.
I was prompted to do this twice - same each time. Enter domain\username in the username field and usual password
Account is then created.
Open Outlook to complete the process and synchronise data with Exchange.
Hope this is helpful to others - again, many thanks for your assistance Martina.
Wayne.

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        - RespondingHttpServer = BESRVCOTEXCH001
        - RespondingRpcProxyServer = BESRVCOTEXCH001
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    X-BEServer: BESRVCOTEXCH001
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